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Bis(amidophenolato)phosphonium: Si−H Hydride Abstraction and Phosphorus‐Ligand Cooperative Activation of C−C Multiple Bonds
The first bis(amidophenolato)phosphonium salts are prepared and fully characterized. The perfluorinated derivative represents the strongest monocationic phosphorus Lewis acid on the fluoride and hydride ion affinity scale isolable to date. This affinity enables new reactions, such as hydride abstrac...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107512/ https://www.ncbi.nlm.nih.gov/pubmed/36367087 http://dx.doi.org/10.1002/chem.202203024 |