Spectroscopic Manifestations and Implications for Catalysis of Quasi‐d(10) Configurations in Formal Gold(III) Complexes

Several gold +I and +III complexes are investigated computationally and spectroscopically, focusing on the d‐configuration and physical oxidation state of the metal center. Density functional theory calculations reveal the non‐negligible electron‐sharing covalent character of the metal‐to‐ligand σ‐b...

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Detalles Bibliográficos
Autores principales: Trifonova, Evgeniya A., Leach, Isaac F., de Haas, Winfried B., Havenith, Remco W. A., Tromp, Moniek, Klein, Johannes E. M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107628/
https://www.ncbi.nlm.nih.gov/pubmed/36508713
http://dx.doi.org/10.1002/anie.202215523

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107628/
https://www.ncbi.nlm.nih.gov/pubmed/36508713
http://dx.doi.org/10.1002/anie.202215523

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