A Dynamic Thermodynamic Resolution Strategy for the Stereocontrolled Synthesis of Streptonigrin

We report that axially chiral biaryl boronic esters can be generated with control of atroposelectivity by a Binol‐mediated dynamic thermodynamic resolution process. These intermediates can be progressed to enantioenriched products through stereoretentive functionalization of the carbon–boron bond. F...

Descripción completa

Detalles Bibliográficos
Autores principales: Valdez Pérez, Luis F., Bachollet, Sylvestre P. J. T., Orlov, Nikolai V., Kopf, Kenji P. M., Harrity, Joseph P. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107650/
https://www.ncbi.nlm.nih.gov/pubmed/36377668
http://dx.doi.org/10.1002/anie.202213692

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107650/
https://www.ncbi.nlm.nih.gov/pubmed/36377668
http://dx.doi.org/10.1002/anie.202213692

Ejemplares similares