Metal‐Free Intermolecular C−H Borylation of N‐Heterocycles at B−B Multiple Bonds

Carbene‐stabilized diborynes of the form LBBL (L=N‐heterocyclic carbene (NHC) or cyclic alkyl(amino)carbene (CAAC)) induce rapid, high yielding, intermolecular ortho‐C−H borylation at N‐heterocycles at room temperature. A simple pyridyldiborene is formed when an NHC‐stabilized diboryne is combined w...

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Detalles Bibliográficos
Autores principales: Brückner, Tobias, Ritschel, Benedikt, Jiménez‐Halla, J. Oscar C., Fantuzzi, Felipe, Duwe, Dario, Markl, Christian, Dewhurst, Rian D., Dietz, Maximilian, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107673/
https://www.ncbi.nlm.nih.gov/pubmed/36440659
http://dx.doi.org/10.1002/anie.202213284

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107673/
https://www.ncbi.nlm.nih.gov/pubmed/36440659
http://dx.doi.org/10.1002/anie.202213284

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