Reversible Dihydrogen Activation and Catalytic H/D Exchange with Group 10 Heterometallic Complexes

Reaction of a hexagonal planar palladium complex featuring a [PdMg(3)H(3)] core with H(2) is reversible and leads to the formation of a new [PdMg(2)H(4)] tetrahydride species alongside an equivalent of a magnesium hydride co‐product [MgH]. While the reversibility of this process prevented isolation...

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Detalles Bibliográficos
Autores principales: Garçon, Martí, Phanopoulos, Andreas, White, Andrew J. P., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107683/
https://www.ncbi.nlm.nih.gov/pubmed/36350647
http://dx.doi.org/10.1002/anie.202213001

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107683/
https://www.ncbi.nlm.nih.gov/pubmed/36350647
http://dx.doi.org/10.1002/anie.202213001

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