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Reversible Dihydrogen Activation and Catalytic H/D Exchange with Group 10 Heterometallic Complexes
Reaction of a hexagonal planar palladium complex featuring a [PdMg(3)H(3)] core with H(2) is reversible and leads to the formation of a new [PdMg(2)H(4)] tetrahydride species alongside an equivalent of a magnesium hydride co‐product [MgH]. While the reversibility of this process prevented isolation...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107683/ https://www.ncbi.nlm.nih.gov/pubmed/36350647 http://dx.doi.org/10.1002/anie.202213001 |