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Effective Formation of New C(sp(2))−S Bonds via Photoactivation of Alkylamine‐based Electron Donor‐Acceptor Complexes

A novel visible light promoted formation of C(Aryl‐)S bonds through electron donor‐acceptor (EDA) complexes of alkylamines with 5‐ and 6‐membered (hetero)arene halides is presented. This represents the first EDA‐based thiolation method not relying on π‐π or a thiolate‐anion‐π interactions and provid...

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Detalles Bibliográficos
Autores principales: Herrera‐Luna, Jorge C., Pérez‐Aguilar, María Carmen, Gerken, Leon, García Mancheño, Olga, Consuelo Jiménez, M., Pérez‐Ruiz, Raúl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107790/
https://www.ncbi.nlm.nih.gov/pubmed/36314234
http://dx.doi.org/10.1002/chem.202203353