Rhodium‐Catalyzed Anti‐Markovnikov Transfer Hydroiodination of Terminal Alkynes

A rhodium‐catalyzed anti‐Markovnikov hydroiodination of aromatic and aliphatic terminal alkynes is reported. Depending on the choice of ligand and substrate, either (E)‐ or (Z)‐configured alkenyl iodides are obtained in high to exclusive isomeric purity. The reaction exhibits a broad substrate scope...

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Detalles Bibliográficos
Autores principales: Boehm, Philip, Kehl, Niklas, Morandi, Bill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107805/
https://www.ncbi.nlm.nih.gov/pubmed/36336665
http://dx.doi.org/10.1002/anie.202214071

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107805/
https://www.ncbi.nlm.nih.gov/pubmed/36336665
http://dx.doi.org/10.1002/anie.202214071

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