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Aerobic C−N Bond Formation through Enzymatic Nitroso‐Ene‐Type Reactions
The biocatalytic oxidation of acylated hydroxylamines enables the direct and selective introduction of nitrogen functionalities by activation of allylic C−H bonds. Utilizing either laccases or an oxidase/peroxidase couple for the formal dehydrogenation of N‐hydroxycarbamates and hydroxamic acids wit...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107922/ https://www.ncbi.nlm.nih.gov/pubmed/36468873 http://dx.doi.org/10.1002/anie.202213671 |