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Aerobic C−N Bond Formation through Enzymatic Nitroso‐Ene‐Type Reactions

The biocatalytic oxidation of acylated hydroxylamines enables the direct and selective introduction of nitrogen functionalities by activation of allylic C−H bonds. Utilizing either laccases or an oxidase/peroxidase couple for the formal dehydrogenation of N‐hydroxycarbamates and hydroxamic acids wit...

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Detalles Bibliográficos
Autores principales: Jäger, Christina, Haase, Mona, Koschorreck, Katja, Urlacher, Vlada B., Deska, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107922/
https://www.ncbi.nlm.nih.gov/pubmed/36468873
http://dx.doi.org/10.1002/anie.202213671