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Electrochemical Kinetics Support a Second Coordination Sphere Mechanism in Metal‐Based Formate Dehydrogenase
Metal‐based formate dehydrogenases are molybdenum or tungsten‐dependent enzymes that catalyze the interconversion between formate and CO(2). According to the current consensus, the metal ion of the catalytic center in its active form is coordinated by 6 S (or 5 S and 1 Se) atoms, leaving no free coo...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107981/ https://www.ncbi.nlm.nih.gov/pubmed/36465058 http://dx.doi.org/10.1002/anie.202212224 |