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Electrochemical Kinetics Support a Second Coordination Sphere Mechanism in Metal‐Based Formate Dehydrogenase

Metal‐based formate dehydrogenases are molybdenum or tungsten‐dependent enzymes that catalyze the interconversion between formate and CO(2). According to the current consensus, the metal ion of the catalytic center in its active form is coordinated by 6 S (or 5 S and 1 Se) atoms, leaving no free coo...

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Detalles Bibliográficos
Autores principales:	Meneghello, Marta, Uzel, Alexandre, Broc, Marianne, Manuel, Rita R., Magalon, Axel, Léger, Christophe, Pereira, Inês A. C., Walburger, Anne, Fourmond, Vincent
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2023
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107981/ https://www.ncbi.nlm.nih.gov/pubmed/36465058 http://dx.doi.org/10.1002/anie.202212224

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