Intertwining Olefin Thianthrenation with Kornblum/Ganem Oxidations: Ene‐type Oxidation to Furnish α,β‐Unsaturated Carbonyls

A widely applicable, practical, and scalable synthetic method for efficient ene‐type double oxidation of alkenes is reported via a two‐step alkenyl thianthrenium umpolung/Kornblum‐Ganem oxidation strategy. This chemo‐ and stereoselective procedure allows easy access to various α,β‐unsaturated carbon...

Descripción completa

Detalles Bibliográficos
Autores principales: Angyal, Péter, Kotschy, András M., Dudás, Ádám, Varga, Szilárd, Soós, Tibor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108043/
https://www.ncbi.nlm.nih.gov/pubmed/36408745
http://dx.doi.org/10.1002/anie.202214096

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108043/
https://www.ncbi.nlm.nih.gov/pubmed/36408745
http://dx.doi.org/10.1002/anie.202214096

Ejemplares similares