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Formation, Reactivity and Decomposition of Aryl Phospha‐Enolates

Two lithium phospha‐enolates [RP=C(Si( i )Pr(3))OLi](2) were prepared by reaction of triisopropyl silyl phosphaethynolate, ( i )Pr(3)SiPCO, with aryl lithium reagents LiR (R=Mes: 1,3,5‐trimethyl phenyl; or Mes*: 1,3,5,‐tri‐tertbutyl phenyl). Monomer/dimer aggregation of the enolates can be modulated...

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Detalles Bibliográficos
Autores principales: Urwin, Stephanie J., Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108052/
https://www.ncbi.nlm.nih.gov/pubmed/36367092
http://dx.doi.org/10.1002/chem.202203081