Copper‐Catalyzed Highly Enantioselective Addition of a Silicon Nucleophile to 3‐Substituted 2H‐Azirines Using an Si−B Reagent

3‐Substituted 2H‐azirines can be considered strained cyclic ketimines, and highly enantioselective addition reactions of silicon nucleophiles to either acyclic or cyclic ketimines have been elusive so far. The present work closes this gap for those azirines by means of a copper‐catalyzed silylation...

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Detalles Bibliográficos
Autores principales: Zhao, Zhi‐Yuan, Cui, Ming, Irran, Elisabeth, Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108078/
https://www.ncbi.nlm.nih.gov/pubmed/36507717
http://dx.doi.org/10.1002/anie.202215032

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108078/
https://www.ncbi.nlm.nih.gov/pubmed/36507717
http://dx.doi.org/10.1002/anie.202215032

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