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Di‐Iron(II) [2+2] Helicates of Bis‐(Dipyrazolylpyridine) Ligands: The Influence of the Ligand Linker Group on Spin State Properties

Four bis[2‐{pyrazol‐1‐yl}‐6‐{pyrazol‐3‐yl}pyridine] ligands have been synthesized, with butane‐1,4‐diyl (L (1)), pyrid‐2,6‐diyl (L (2)), benzene‐1,2‐dimethylenyl (L (3)) and propane‐1,3‐diyl (L (4)) linkers between the tridentate metal‐binding domains. L (1) and L (2) form [Fe(2)(μ−L)(2)]X(4) (X(−)=...

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Detalles Bibliográficos
Autores principales: Kulmaczewski, Rafal, Armstrong, Isaac T., Catchpole, Pip, Ratcliffe, Emily S. J., Vasili, Hari Babu, Warriner, Stuart L., Cespedes, Oscar, Halcrow, Malcolm A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108139/
https://www.ncbi.nlm.nih.gov/pubmed/36382594
http://dx.doi.org/10.1002/chem.202202578