How Bases Catalyze Diels‐Alder Reactions

We have quantum chemically studied the base‐catalyzed Diels‐Alder (DA) reaction between 3‐hydroxy‐2‐pyrone and N‐methylmaleimide using dispersion‐corrected density functional theory. The uncatalyzed reaction is slow and is preceded by the extrusion of CO(2) via a retro‐DA reaction. Base catalysis, f...

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Detalles Bibliográficos
Autores principales: Yu, Song, Tiekink, Eveline H., Vermeeren, Pascal, Bickelhaupt, F. Matthias, Hamlin, Trevor A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108159/
https://www.ncbi.nlm.nih.gov/pubmed/36330879
http://dx.doi.org/10.1002/chem.202203121

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108159/
https://www.ncbi.nlm.nih.gov/pubmed/36330879
http://dx.doi.org/10.1002/chem.202203121

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