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How Bases Catalyze Diels‐Alder Reactions
We have quantum chemically studied the base‐catalyzed Diels‐Alder (DA) reaction between 3‐hydroxy‐2‐pyrone and N‐methylmaleimide using dispersion‐corrected density functional theory. The uncatalyzed reaction is slow and is preceded by the extrusion of CO(2) via a retro‐DA reaction. Base catalysis, f...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108159/ https://www.ncbi.nlm.nih.gov/pubmed/36330879 http://dx.doi.org/10.1002/chem.202203121 |