Low‐Valent M( x )Al(3) Cluster Salts with Tetrahedral [SiAl(3)](+) and Trigonal‐Bipyramidal [M(2)Al(3)](2+) Cores (M=Si/Ge)

Schnöckel's [(AlCp*)(4)] and Jutzi's [SiCp*][B(C(6)F(5))(4)] (Cp*=C(5)Me(5)) are landmarks in modern main‐group chemistry with diverse applications in synthesis and catalysis. Despite the isoelectronic relationship between the AlCp* and the [SiCp*](+) fragments, their mutual reactivity is...

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Detalles Bibliográficos
Autores principales: Dabringhaus, Philipp, Zedlitz, Silja, Giarrana, Luisa, Scheschkewitz, David, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108233/
https://www.ncbi.nlm.nih.gov/pubmed/36479813
http://dx.doi.org/10.1002/anie.202215170

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108233/
https://www.ncbi.nlm.nih.gov/pubmed/36479813
http://dx.doi.org/10.1002/anie.202215170

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