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Low‐Valent M( x )Al(3) Cluster Salts with Tetrahedral [SiAl(3)](+) and Trigonal‐Bipyramidal [M(2)Al(3)](2+) Cores (M=Si/Ge)
Schnöckel's [(AlCp*)(4)] and Jutzi's [SiCp*][B(C(6)F(5))(4)] (Cp*=C(5)Me(5)) are landmarks in modern main‐group chemistry with diverse applications in synthesis and catalysis. Despite the isoelectronic relationship between the AlCp* and the [SiCp*](+) fragments, their mutual reactivity is...
Autores principales: | Dabringhaus, Philipp, Zedlitz, Silja, Giarrana, Luisa, Scheschkewitz, David, Krossing, Ingo |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108233/ https://www.ncbi.nlm.nih.gov/pubmed/36479813 http://dx.doi.org/10.1002/anie.202215170 |
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