Rhodium‐Catalyzed Formylation of Unactivated Alkyl Chlorides to Aldehydes

The first rhodium‐catalyzed formylation of non‐activated alkyl chlorides with syn gas (H(2)/CO) allows to produce aldehydes in high yields (25 examples). A catalyst optimization study revealed Rh(acac)(CO)(2) in the presence of 1,3‐bisdiphenylphosphinopropane (DPPP) as the most active catalyst syste...

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Detalles Bibliográficos
Autores principales: Wang, Peng, Wang, Yaxin, Neumann, Helfried, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108320/
https://www.ncbi.nlm.nih.gov/pubmed/36342300
http://dx.doi.org/10.1002/chem.202203342

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108320/
https://www.ncbi.nlm.nih.gov/pubmed/36342300
http://dx.doi.org/10.1002/chem.202203342

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