Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp(3))−H Bond Insertion

The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic C(sp(3))−H bond has been achieved for the first time during a silver‐catalyzed carbene/alkyne metathesis (CAM) process. A Tp(x)‐containing silver complex first promotes the generation of a donor‐acceptor silver carb...

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Detalles Bibliográficos
Autores principales: Díaz‐Jiménez, Àlex, Monreal‐Corona, Roger, Poater, Albert, Álvarez, María, Borrego, Elena, Pérez, Pedro J., Caballero, Ana, Roglans, Anna, Pla‐Quintana, Anna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108323/
https://www.ncbi.nlm.nih.gov/pubmed/36345831
http://dx.doi.org/10.1002/anie.202215163

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108323/
https://www.ncbi.nlm.nih.gov/pubmed/36345831
http://dx.doi.org/10.1002/anie.202215163

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