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Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp(3))−H Bond Insertion
The trapping of the elusive vinylogous position of a vinyl carbene with an aliphatic C(sp(3))−H bond has been achieved for the first time during a silver‐catalyzed carbene/alkyne metathesis (CAM) process. A Tp(x)‐containing silver complex first promotes the generation of a donor‐acceptor silver carb...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10108323/ https://www.ncbi.nlm.nih.gov/pubmed/36345831 http://dx.doi.org/10.1002/anie.202215163 |