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Chemoselective Decarboxylative Oxygenation of Carboxylic Acids To Access Ketones, Aldehydes, and Peroxides

[Image: see text] Reported here is a photocatalytic strategy for the chemoselective decarboxylative oxygenation of carboxylic acids using Ce(III) catalysts and O(2) as the oxidant. By simply changing the base employed, we demonstrate that the selectivity of the reaction can be channeled to favor hyd...

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Detalles Bibliográficos
Autores principales: Guan, Renpeng, Chen, Guanhong, Bennett, Elliot L., Huang, Zhiliang, Xiao, Jianliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10111417/
https://www.ncbi.nlm.nih.gov/pubmed/37013983
http://dx.doi.org/10.1021/acs.orglett.3c00649