Unveiling the Latent Reactivity of Cp* Ligands (C(5)Me(5)(–)) toward Carbon Nucleophiles on an Iridium Complex

[Image: see text] The divergent reactivity of the cationic iridium complex [(η(5)-C(5)Me(5))IrCl(PMe(2)Ar(Dipp2))](+) (Ar(Dipp2) = C(6)H(3)–2,6-(C(6)H(3)–2,6-(i)Pr(2))(2)) toward organolithium and Grignard reagents is described. The noninnocent behavior of the Cp* ligand, a robust spectator in the m...

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Detalles Bibliográficos
Autores principales: Pita-Milleiro, Alejandra, Alférez, Macarena G., Moreno, Juan J., Espada, María F., Maya, Celia, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10114086/
https://www.ncbi.nlm.nih.gov/pubmed/37010818
http://dx.doi.org/10.1021/acs.inorgchem.2c04381

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10114086/
https://www.ncbi.nlm.nih.gov/pubmed/37010818
http://dx.doi.org/10.1021/acs.inorgchem.2c04381

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