Additivity of Diene Substituent Gibbs Free Energy Contributions for Diels–Alder Reactions between Me(2)C=CMe(2) and Substituted Cyclopentadienes

[Image: see text] Systematic computational studies of pericyclic Diels–Alder reactions between (H(3)C)(2)C=C(CH(3))(2), 1, and all permutations of substituted cyclopentadienes c-C(5)R(1)R(2)R(3)R(4)R(5a)R(5b) (R = H, CH(3), CF(3), F) allowed isolation of substitutional effects on Gibbs free energy b...

Descripción completa

Detalles Bibliográficos
Autores principales: Flemming, Austin S., Dutmer, Brendan C., Gilbert, Thomas M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10116529/
https://www.ncbi.nlm.nih.gov/pubmed/37091433
http://dx.doi.org/10.1021/acsomega.3c00831

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10116529/
https://www.ncbi.nlm.nih.gov/pubmed/37091433
http://dx.doi.org/10.1021/acsomega.3c00831

Ejemplares similares