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Additivity of Diene Substituent Gibbs Free Energy Contributions for Diels–Alder Reactions between Me(2)C=CMe(2) and Substituted Cyclopentadienes

[Image: see text] Systematic computational studies of pericyclic Diels–Alder reactions between (H(3)C)(2)C=C(CH(3))(2), 1, and all permutations of substituted cyclopentadienes c-C(5)R(1)R(2)R(3)R(4)R(5a)R(5b) (R = H, CH(3), CF(3), F) allowed isolation of substitutional effects on Gibbs free energy b...

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Detalles Bibliográficos
Autores principales:	Flemming, Austin S., Dutmer, Brendan C., Gilbert, Thomas M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10116529/ https://www.ncbi.nlm.nih.gov/pubmed/37091433 http://dx.doi.org/10.1021/acsomega.3c00831

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