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4,4′-Dicyano- versus 4,4′-Difluoro-BODIPYs in Chemoselective Postfunctionalization Reactions: Synthetic Advantages and Applications

[Image: see text] The presence of F or CN substituents at boron in BODIPYs causes a dramatic effect on their reactivity, which allows their chemoselective postfunctionalization. Thus, whereas 1,3,5,7-tetramethyl B(CN)(2)-BODIPYs displayed enhanced reactivity in Knoevenagel condensations with aldehyd...

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Detalles Bibliográficos
Autores principales: Ventura, Juan, Uriel, Clara, Gómez, Ana M., Avellanal-Zaballa, Edurne, Bañuelos, Jorge, Rebollar, Esther, Garcia-Moreno, Inmaculada, López, J. Cristobal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127263/
https://www.ncbi.nlm.nih.gov/pubmed/37026858
http://dx.doi.org/10.1021/acs.orglett.3c00476