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A Nickel-Catalyzed Cross-Electrophile Coupling Reaction of 1,3-Dimesylates for Alkylcyclopropane Synthesis: Investigation of Stereochemical Outcomes and Radical Lifetimes

[Image: see text] Understanding mechanistic details of the nickel-catalyzed coupling reactions of Csp(3) alcohol derivatives is key to developing selective reactions of this widely prevalent functional group. In this manuscript, we utilize a combination of experimental data and DFT studies to define...

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Detalles Bibliográficos
Autores principales: Chen, Pan-Pan, McGinnis, Tristan M., Lin, Patricia C., Hong, Xin, Jarvo, Elizabeth R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127265/
https://www.ncbi.nlm.nih.gov/pubmed/37123596
http://dx.doi.org/10.1021/acscatal.3c00905