Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides

[Image: see text] A catalytic asymmetric reaction between allenes, bis(pinacolato)diboron, and allylic gem-dichlorides is reported. The method involves the coupling of a catalytically generated allyl copper species with the allylic gem-dichloride and provides chiral internal 1,5-dienes featuring (Z)...

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Detalles Bibliográficos
Autores principales: Piñeiro-Suárez, Martín, Álvarez-Constantino, Andrés M., Fañanás-Mastral, Martín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127276/
https://www.ncbi.nlm.nih.gov/pubmed/37123595
http://dx.doi.org/10.1021/acscatal.3c00536

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127276/
https://www.ncbi.nlm.nih.gov/pubmed/37123595
http://dx.doi.org/10.1021/acscatal.3c00536

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