Base- and Additive-Free Carbon Dioxide Hydroboration to Methoxyboranes Catalyzed by Non-Pincer-Type Mn(I) Complexes

[Image: see text] Well-defined, bench stable Mn(I) non-pincer-type complexes were tested as earth-abundant transition metal catalysts for the selective reduction of CO(2) to boryl-protected MeOH in the presence of pinacolborane (HBpin). Essentially, quantitative yields were obtained under mild react...

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Detalles Bibliográficos
Autores principales: Kostera, Sylwia, Weber, Stefan, Blaha, Ines, Peruzzini, Maurizio, Kirchner, Karl, Gonsalvi, Luca
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127281/
https://www.ncbi.nlm.nih.gov/pubmed/37123593
http://dx.doi.org/10.1021/acscatal.3c00020

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127281/
https://www.ncbi.nlm.nih.gov/pubmed/37123593
http://dx.doi.org/10.1021/acscatal.3c00020

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