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Base- and Additive-Free Carbon Dioxide Hydroboration to Methoxyboranes Catalyzed by Non-Pincer-Type Mn(I) Complexes
[Image: see text] Well-defined, bench stable Mn(I) non-pincer-type complexes were tested as earth-abundant transition metal catalysts for the selective reduction of CO(2) to boryl-protected MeOH in the presence of pinacolborane (HBpin). Essentially, quantitative yields were obtained under mild react...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10127281/ https://www.ncbi.nlm.nih.gov/pubmed/37123593 http://dx.doi.org/10.1021/acscatal.3c00020 |