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The Origin of Anion−π Autocatalysis

[Image: see text] The autocatalysis of epoxide-opening ether cyclizations on the aromatic surface of anion−π catalysts stands out as a leading example of emergent properties expected from the integration of unorthodox interactions into catalysis. A working hypothesis was proposed early on, but the m...

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Detalles Bibliográficos
Autores principales: Gutiérrez López, M. Ángeles, Tan, Mei-Ling, Frontera, Antonio, Matile, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10131205/
https://www.ncbi.nlm.nih.gov/pubmed/37124310
http://dx.doi.org/10.1021/jacsau.2c00656