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Formation of a P(16)(2–) Ink from Elemental Red Phosphorus in a Thiol–Amine Mixture

[Image: see text] A P(16)(2–) polyphosphide dianion ink was produced by the reaction of red phosphorus with a binary thiol–amine mixture of ethanethiol (ET) and ethylenediamine (en). The polyphosphide was identified by solution (31)P NMR spectroscopy and electrospray ionization mass spectrometry. Th...

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Detalles Bibliográficos
Autores principales: Strumolo, Marissa J., Eremin, Dmitry B., Wang, Shuai, Mora Perez, Carlos, Prezhdo, Oleg V., Figueroa, Joshua S., Brutchey, Richard L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10131223/
https://www.ncbi.nlm.nih.gov/pubmed/37039460
http://dx.doi.org/10.1021/acs.inorgchem.3c00370