Tuning symmetry and magnetic blocking of an exchange-coupled lanthanide ion in isomeric, tetrametallic complexes: [LnCl(6)(TiCp(2))(3)]

The synthesis and magnetic properties of two pairs of isomeric, exchange-coupled complexes, [LnCl(6)(TiCp(2))(3)] (Ln = Gd, Tb), are reported. In each isomeric pair, the central lanthanide ion adopts either a pseudo-octahedral (O-Ln) or trigonal prismatic geometry (TP-Ln) yielding complexes with C(1...

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Detalles Bibliográficos
Autores principales: Jiang, Ningxin, Nakritskaia, Daria D., Xie, Jiaze, Ramanathan, Arun, Varganov, Sergey A., La Pierre, Henry S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10132101/
https://www.ncbi.nlm.nih.gov/pubmed/37123176
http://dx.doi.org/10.1039/d2sc06263a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10132101/
https://www.ncbi.nlm.nih.gov/pubmed/37123176
http://dx.doi.org/10.1039/d2sc06263a

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