A rare isocyanide derived from an unprecedented neutral yttrium(ii) bis(amide) complex

A room temperature stable complex formulated as Y(NHAr*)(2) has been prepared, where Ar* = 2,6-(2,4,6-((i)Pr)(3)C(6)H(2))C(6)H(3), by KC(8) reduction of ClY(NHAr*)(2). Based on EPR evidence, Y(NHAr*)(2) is an example of a d(1) Y(ii) complex with significant delocalization of the unpaired electron de...

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Detalles Bibliográficos
Autores principales: Jena, Rashmi, Benner, Florian, Delano, Francis, Holmes, Daniel, McCracken, John, Demir, Selvan, Odom, Aaron L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10132164/
https://www.ncbi.nlm.nih.gov/pubmed/37123180
http://dx.doi.org/10.1039/d3sc00171g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10132164/
https://www.ncbi.nlm.nih.gov/pubmed/37123180
http://dx.doi.org/10.1039/d3sc00171g

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