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A rare isocyanide derived from an unprecedented neutral yttrium(ii) bis(amide) complex
A room temperature stable complex formulated as Y(NHAr*)(2) has been prepared, where Ar* = 2,6-(2,4,6-((i)Pr)(3)C(6)H(2))C(6)H(3), by KC(8) reduction of ClY(NHAr*)(2). Based on EPR evidence, Y(NHAr*)(2) is an example of a d(1) Y(ii) complex with significant delocalization of the unpaired electron de...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10132164/ https://www.ncbi.nlm.nih.gov/pubmed/37123180 http://dx.doi.org/10.1039/d3sc00171g |