Spin-Forbidden Addition of Molecular Oxygen to Stable Enol Intermediates—Decarboxylation of 2-Methyl-1-tetralone-2-carboxylic Acid

The deprotonation of an organic substrate is a common preactivation step for the enzymatic cofactorless addition of O [Formula: see text] to this substrate, as it promotes charge-transfer between the two partners, inducing intersystem crossing between the triplet and singlet states involved in the p...

Descripción completa

Detalles Bibliográficos
Autores principales: Ortega, Pablo, Gil-Guerrero, Sara, González-Sánchez, Lola, Sanz-Sanz, Cristina, Jambrina, Pablo G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10138960/
https://www.ncbi.nlm.nih.gov/pubmed/37108586
http://dx.doi.org/10.3390/ijms24087424

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10138960/
https://www.ncbi.nlm.nih.gov/pubmed/37108586
http://dx.doi.org/10.3390/ijms24087424

Ejemplares similares