Cargando…
Spin-Forbidden Addition of Molecular Oxygen to Stable Enol Intermediates—Decarboxylation of 2-Methyl-1-tetralone-2-carboxylic Acid
The deprotonation of an organic substrate is a common preactivation step for the enzymatic cofactorless addition of O [Formula: see text] to this substrate, as it promotes charge-transfer between the two partners, inducing intersystem crossing between the triplet and singlet states involved in the p...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2023
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10138960/ https://www.ncbi.nlm.nih.gov/pubmed/37108586 http://dx.doi.org/10.3390/ijms24087424 |