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Taming Super-Reduced Bi(2)(3–) Radicals with Rare Earth Cations
[Image: see text] Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules. The first series contains a bridging diamagnetic Bi(2)(2–) anion, (Cp*(2)RE)(2)(μ-η(2):η(2)-Bi(2)), 1-RE (where Cp* = pentamethylcyclopentadienyl; RE = Gd (1-Gd), Tb (1-Tb), Dy (1-Dy), Y (1-Y))...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141245/ https://www.ncbi.nlm.nih.gov/pubmed/37043770 http://dx.doi.org/10.1021/jacs.3c01058 |