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Taming Super-Reduced Bi(2)(3–) Radicals with Rare Earth Cations

[Image: see text] Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules. The first series contains a bridging diamagnetic Bi(2)(2–) anion, (Cp*(2)RE)(2)(μ-η(2):η(2)-Bi(2)), 1-RE (where Cp* = pentamethylcyclopentadienyl; RE = Gd (1-Gd), Tb (1-Tb), Dy (1-Dy), Y (1-Y))...

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Detalles Bibliográficos
Autores principales: Zhang, Peng, Nabi, Rizwan, Staab, Jakob K., Chilton, Nicholas F., Demir, Selvan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141245/
https://www.ncbi.nlm.nih.gov/pubmed/37043770
http://dx.doi.org/10.1021/jacs.3c01058

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