Dirhodium(II)/Phosphine Catalyst with Chiral Environment at Bridging Site and Its Application in Enantioselective Atropisomer Synthesis

[Image: see text] A dirhodium(II)/phosphine catalyst with a chiral environment at the bridging site was developed for the asymmetric arylation of phenanthrene-9,10-diones with arylboronic acids. In contrast to the classic chiral bridging carboxylic acid (or derivatives) ligand strategy of bimetallic...

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Detalles Bibliográficos
Autores principales: Shi, Lei, Xue, Xiaoping, Hong, Biqiong, Li, Qigang, Gu, Zhenhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141619/
https://www.ncbi.nlm.nih.gov/pubmed/37122446
http://dx.doi.org/10.1021/acscentsci.2c01207

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10141619/
https://www.ncbi.nlm.nih.gov/pubmed/37122446
http://dx.doi.org/10.1021/acscentsci.2c01207

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