Recombination of X-ray-Generated Radical Ion Pairs in Alkane Solution Assembles Optically Inaccessible Exciplexes from a Series of Perfluorinated para-Oligophenylenes with N,N-Dimethylaniline

We demonstrate that a series of perfluorinated para-oligophenylenes C(6)F(5)-(C(6)F(4))(n)-C(6)F(5) (n = 1–3) produce exciplexes with N,N-dimethylaniline (DMA) in degassed X-irradiated n-dodecane solutions. The optical characterization of the compounds shows that their short fluorescence lifetimes (...

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Detalles Bibliográficos
Autores principales: Nikul’shin, Pavel V., Fedunov, Roman G., Kuibida, Leonid V., Maksimov, Alexander M., Glebov, Evgeni M., Stass, Dmitri V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10142361/
https://www.ncbi.nlm.nih.gov/pubmed/37108728
http://dx.doi.org/10.3390/ijms24087568

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10142361/
https://www.ncbi.nlm.nih.gov/pubmed/37108728
http://dx.doi.org/10.3390/ijms24087568

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