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New Insight into the Reactivity of S,S-Bis-ylide

The present work focuses on the reactivity of S,S-bis-ylide 2, which presents a strong nucleophilic character, as evidenced by reactions with methyl iodide and CO(2), affording C-methylated salts 3 and betaine 4, respectively. The derivatization of betaine 4 affords the corresponding ester derivativ...

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Detalles Bibliográficos
Autores principales: Authesserre, Ugo, Swamy, V. S. V. S. N., Saffon-Merceron, Nathalie, Baceiredo, Antoine, Kato, Tsuyoshi, Maerten, Eddy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10142965/
https://www.ncbi.nlm.nih.gov/pubmed/37110528
http://dx.doi.org/10.3390/molecules28083295