The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes

Acid-base characteristics (acidity, pKa, and hydricity, ΔG°(H−) or k(H−)) of metal hydride complexes could be a helpful value for forecasting their activity in various catalytic reactions. Polarity of the M–H bond may change radically at the stage of formation of a non-covalent adduct with an acidic...

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Detalles Bibliográficos
Autores principales: Osipova, Elena S., Kovalenko, Sergey A., Gulyaeva, Ekaterina S., Kireev, Nikolay V., Pavlov, Alexander A., Filippov, Oleg A., Danshina, Anastasia A., Valyaev, Dmitry A., Canac, Yves, Shubina, Elena S., Belkova, Natalia V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10143952/
https://www.ncbi.nlm.nih.gov/pubmed/37110601
http://dx.doi.org/10.3390/molecules28083368

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10143952/
https://www.ncbi.nlm.nih.gov/pubmed/37110601
http://dx.doi.org/10.3390/molecules28083368

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