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Steric hindrance, ligand ejection and associated photocytotoxic properties of ruthenium(II) polypyridyl complexes

Two ruthenium(II) polypyridyl complexes were prepared with the {Ru(phen)(2)}(2+) moiety and a third sterically non-hindering bidentate ligand, namely 2,2′-dipyridylamine (dpa) and N-benzyl-2,2′-dipyridylamine (Bndpa). Hence, complexes [Ru(phen)(2)(dpa)](PF(6))(2) (1) and [Ru(phen)(2)(Bndpa)](PF(6))(...

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Detalles Bibliográficos
Autores principales: Herrera-Ramírez, Piedad, Berger, Sarah Alina, Josa, Dana, Aguilà, David, Caballero, Ana B., Fontova, Pere, Soto-Cerrato, Vanessa, Martínez, Manuel, Gamez, Patrick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer International Publishing 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10149480/
https://www.ncbi.nlm.nih.gov/pubmed/37059909
http://dx.doi.org/10.1007/s00775-023-01998-z