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Applying Na/Co(ii) bimetallic partnerships to promote multiple Co–H exchanges in polyfluoroarenes
Heterobimetallic base NaCo(HMDS)(3) [HMDS = N(SiMe(3))(2)] enables regioselective di-cobaltation of activated polyfluoroarenes under mild reaction conditions. For 1,3,5-C(6)H(2)X(3) (X= Cl, F), NaCo(HMDS)(3) in excess at 80 °C impressively induces the collective cleavage of five bonds (two C–H and t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10152514/ https://www.ncbi.nlm.nih.gov/pubmed/37060131 http://dx.doi.org/10.1039/d3cc01216f |