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Direct C2–H alkylation of indoles driven by the photochemical activity of halogen-bonded complexes

A light-driven metal-free protocol for the synthesis of sulfone-containing indoles under mild conditions is reported. Specifically, the process is driven by the photochemical activity of halogen-bonded complexes formed upon complexation of a sacrificial donor, namely 1,4-diazabicyclo[2.2.2]octane (D...

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Detalles Bibliográficos
Autores principales: Mamone, Martina, Gentile, Giuseppe, Dosso, Jacopo, Prato, Maurizio, Filippini, Giacomo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155616/
https://www.ncbi.nlm.nih.gov/pubmed/37153645
http://dx.doi.org/10.3762/bjoc.19.42