A metal π-Lewis base activation model for Pd-catalyzed hydroamination of amines and 1,3-dienes

As a general mechanism proposal, a Pd(ii)–H migration insertion process is not able to well explicate the Pd-catalyzed hydroamination of amines and 1,3-dienes. Here we demonstrate that 1,3-dienes form electron-neutral and HOMO-raised η(2)-complexes with Pd(0) via π-Lewis base activation, which under...

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Detalles Bibliográficos
Autores principales: Yan, Xiao, Yang, Xiu-Ming, Yan, Peng, Zhao, Bo, Zeng, Rong, Pan, Bin, Chen, Ying-Chun, Zhu, Lei, Ouyang, Qin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155909/
https://www.ncbi.nlm.nih.gov/pubmed/37152262
http://dx.doi.org/10.1039/d2sc05835a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155909/
https://www.ncbi.nlm.nih.gov/pubmed/37152262
http://dx.doi.org/10.1039/d2sc05835a

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