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Chirally and chemically reversible Strecker reaction

In the pursuit of a credible mechanism for the abiotic synthesis of α-amino acids, solid-state asymmetric Strecker/retro-Strecker reactions have been demonstrated. Asymmetric addition of cyanide to enantiomorphic crystals of achiral imines proceeded to produce enantioenriched aminonitriles. Moreover...

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Detalles Bibliográficos
Autores principales: Machida, Yutaro, Tanaka, Yudai, Masuda, Yuya, Kimura, Aya, Kawasaki, Tsuneomi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155917/
https://www.ncbi.nlm.nih.gov/pubmed/37152252
http://dx.doi.org/10.1039/d3sc00359k