Chiral spirosiladiphosphines: ligand development and applications in Rh-catalyzed asymmetric hydrosilylation/cyclization of 1,6-enynes with enhanced reactivity

Spirodiphosphines have been successfully applied in various asymmetric catalytic transformations. However, controlling the coordinating conformations by the direct displacement of the spiro atom remains elusive. Herein, we report the application of Si-centered spirodiphosphine (Si-SDP) ligands in th...

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Detalles Bibliográficos
Autores principales: Hou, Fei, Liu, Minjie, Ru, Tong, Tan, Zequn, Ning, Yingtang, Chen, Fen-Er
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155919/
https://www.ncbi.nlm.nih.gov/pubmed/37152270
http://dx.doi.org/10.1039/d2sc06349b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155919/
https://www.ncbi.nlm.nih.gov/pubmed/37152270
http://dx.doi.org/10.1039/d2sc06349b

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